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Showing posts with label molybdenite. Show all posts
Showing posts with label molybdenite. Show all posts

Saturday, 9 March 2024

KINGSGATE MINES Part 3

THE GEOLOGY OF KINGSGATE

The casual visitor may overlook the intimate relationship between the ore bearing pipes and the granite/metamorphics contact, but the miners were well aware that the ore bodies were always found within the granite and never more than a few hundred metres from its margin. That this is more than a co-incidence was borne out during mining when it was often found that the pipes dipped into the earth more or less parallel to the contact.

It will be necessary to examine briefly the geological structure of the district to understand the origin of the mineral deposits. The rocks throughout New England reveal a complex history of marine and nonmarine sedimentation, explosive volcanic activity and widespread intrusion of granitic magma. This is consistent with what is found today along growing continental margins, where marine sediments are subducted beneath thicker continental crust by plate movements. Such a situation occurs today in Japan, which probably resembles the New England of the late Palaeozoic era. At Kingsgate, metamorphosed sediments of probable Permian age have been intruded by late Permian/early Triassic granite. Mineralisation is confined to 70 or more roughly cylindrical ore bodies within the granite, at a short distance from its intrusive contact.

Molybdenum mineralisation in New England is mostly located in a NE/SW trending zone including the deposits at Wunglebung, Deepwater, Glen Eden, Kingsgate and Booralong. At each place the mineralisation is near an intrusive granite margin, sometimes in pipe formations (as at Kingsgate and Deepwater) and sometimes associated with aplite and pegmatite bodies within the granite (as at Booralong). Similar relationships have been observed in North Queensland deposits. It would appear that volatile components of the magma, containing quartz, sulfur, bismuth and molybdenum in solution, have crystallised within the mostly solidified granite at a late stage of the cooling of the intrusion.

The most prominent of the igneous rocks at Kingsgate is a coarse, mottled grey adamellite, rich in quartz and orthoclase, nonporphyritic and with no apparent structure. It differs noticeably from the tin bearing granites seen, for example, at Torrington. The common dark minerals within the granite are biotite and hornblende. However, this rock does not appear to be the actual host rock for the deposits, which is more likely to a very acid granite usually not seen in outcrop but generally reduced to a thick gravelly soil. Several other granitic bodies also outcrop in the area. The former sedimentary rocks intruded by the granite may be seen in road cuttings below the mines and along the Yarrow River. They are essentially altered siltstone of presumed Permian age. No fossils are known from these rocks at Kingsgate, but Permian marine fossils have been found in similar rocks further south.

There has been considerable speculation as to the reasons why the Kingsgate mineralisation occurs in the way it does. The best that can be said is that the pipes are separate intrusions into the main plutonic mass, whose location has been controlled by the pressure and temperature conditions prevailing at the time. The pipes are very irregular in shape and structure and frequently change direction, dip and diameter as they are followed downwards. Some are characterised by branches, others by their variation in diameter from a few centimetres to many metres across. In some the minerals completely fill the pipe, in others there are open spaces lined with huge quartz crystals. All are of the same essential character, being composed in part of granite in which the felspar has been altered to sericite, in part of quartz and in part of veins and segregations of ore minerals.

Sach's Pipe (the Old 45) has been studied in some detail. More information on individual pipes is to be found in the next chapter.


Song Studies. Bible studies based on hymns and songs
Shoalhaven District Geology.

Wednesday, 6 March 2024

KINGSGATE MINES Part 2

KINGSGATE MINERALS

(This is the second chapter of this booklet on Kingsgate Mines.) When I get time, I'll fix up all the chemical formulae.

The modern visitor to Kingsgate mines is probably hoping to find specimens of the minerals for which the place is justly famous. It is a classic locality for quartz crystals and molybdenite in particular but many more minerals are likely to be found on the dumps. More than 30 different minerals have been recorded at Kingsgate and the collector should have no difficulty finding specimens of at least 10 of these. They fall into two categories: ore minerals and rock-forming minerals and this is the order in which we shall examine them.


ORE MINERALS

Molybdenite, MoS2. This is the most obvious of the metallic minerals, easily recognised by its high metallic lustre and extreme softness. With a hardness of only 1 - 1.5, it will readily mark the fingers when handled. It is widespread on the mullock heaps, standing out against the white quartz in which it is frequently embedded. Careful searching will reveal specimens showing the hexagonal crystal shape and others displaying alteration to the yellow mineral ferrimolybdite. Specimens may also be found in which the crystals are found together as small rosettes.
Bismuth, Bi. A much more difficult mineral to find on the dumps, due to its greater value. Native bismuth is a brittle silver-white mineral with a distinctly pinkish tinge. It is relatively soft (2 - 2.5) and has a shiny silver-white streak, which is easily seen when specimens are rubbed against a piece of white quartz. The bismuth was usually found as masses between quartz crystals and occasionally as wires within white or transparent quartz.
Wolframite (variety ferberite), (Fe,Mn)WO4. A dense, brown to black mineral, wolframite is found scattered in pieces through the dumps. It has a prominent cleavage, making it easy to recognise because of the flat, lustrous surfaces created. It is comparatively scarce, but easy to recognise.
Cassiterite, SnO2 (tinstone). It was this mineral which the first prospectors were seeking at Kingsgate in 1872. It is scarce, being found in few of the pipes. Cassiterite is a hard, dense mineral, usually brown or black. Despite its colour, its streak is white unlike any of the other dark minerals likely to be found at Kingsgate.
Arsenopyrite, FeAsS (mispickel, arsenical pyrites). Another mineral with a metallic lustre, arsenopyrite is silver-white in colour with a black streak. It is much harder than bismuth and easily distinguished from it by its streak. It occurs plentifully in some pipes, usually as large masses in white reef quartz but is scarce in most.
Bismuthinite, Bi2S3. This is a rare mineral which was encountered in some pipes at Kingsgate in masses several kilograms in weight. It resembles native bismuth, with which it is often found, but is somewhat darker both in colour and streak.
Ferrimolybdite, Fe2(MoO4)3.8H2O (molybdite, molybdic ochre). Once thought to be molybdenum oxide, this canary yellow mineral is a common alteration product of molybdenite, with which it is often found. When found as crystals it occurs as tufts of acicular crystals up to 1 cm long.
Powellite, CaMoO4, with some tungsten substituting for molybdenum. Powellite forms by the alteration of molybdenite and is itself altered to ferrimolybdite. It is a rare mineral found in tetragonal crystals of bipyramidal habit of hardness 3.5 - 4. Its colour varies from yellow through greenish blue to nearly black.
Bismite, Bi2O3 (bismuth ochre). This is a somewhat earthy yellow to greyish green mineral found as an oxidation product of bismuth and bismuthinite, with which it is likely to be found. It occurs as fibrous masses in cavities in the quartz.
Bismutite, (BiO)2CO3. Another secondary bismuth mineral, this was one of the first bismuth minerals to be recognised at Kingsgate. It occurs as straw-yellow pseudomorphs after bismuthinite. It has sometimes been mistaken for gold by beginners, as it occasionally turns up in the prospector's dish. Unlike gold, particles of bismutite can easily be crushed to a powder.
Scorodite, FeAsO4.2H2O forms as an oxidation product of arsenopyrite. It is found as green botryoidal masses lining cavities in reef quartz formerly occupied by arsenopyrite.
Pyrrhotite, FeS, is occasionally found on the dumps. It has a metallic lustre, with a typically yellow-grey colour. Its streak is dark greyish black. The mineral is frequently slightly magnetic and oxidises on exposure to an iridescent surface.
Pyrite, FeS2, is occasionally found as pale brass-yellow cubes with an intense metallic lustre. Its streak is typically greenish black.
Chalcopyrite, CuFeS2, resembles pyrite but has a more golden colour. Surfaces are frequently tarnished and iridescent.
Galena, PbS, occurs from time to time as brilliant grey cubes, which cleave easily in a cubic fashion. Galena is denser than most minerals with a metallic lustre.
Galenobismutite, PbBi2S4, has been reported as greenish silver coloured masses up to 5cm across in molybdenite.
Ikunolite, Bi4(S,Se)3, is a rare mineral which has been reported at Kingsgate as plates and foliated masses with a prominent basal cleavage, lead-grey in colour.
Joseite, Bi3TeS, is another rare mineral reported from Kingsgate. It is a soft greyish mineral displaying one perfect cleavage.
Cosalite, Pb2Bi2S5, has been found from time to time as metallic lead-grey needle-like crystals.
Pyrargyrite, Ag3SbS3 (ruby silver), has been reported as soft, deep red prisms. The crystals display an adamantine lustre.
Gold, Au and Silver, Ag, have appeared in significant quantities in some chemical analyses of ore samples.
Brookite, gudmundite, sphalerite, chalcocite, covellite, marcasite, smythite, goethite, ilsemannite, tungstite and wulfenite have all become recorded at various times.

ROCK-FORMING MINERALS
Quartz (SiO2) is the overwhelmingly obvious mineral to be found at Kingsgate. The pipes consist essentially of quartz in which the ore minerals are embedded. The quartz varies a great deal from massive


to individual crystals up to 200 kg in weight, from milky to glass clear, smoky and rutilated. It is found as single crystals and as a variety of twin types. It is found alone and in company with crystals of the various ore minerals. Specimens of all types can still be found on the dumps and have made their way into collections all over Australia and beyond.
Rock Crystal. This is the term applied to the colourless variety of quartz which is much sought after for faceting, carving and just as specimens. It is not as simple as it might seem to find completely flawless material. Thousands of collectors have been to Kingsgate over the years to gather just such specimens. It will probably be necessary to search the more remote dumps and to dig deeply into them to locate the best material.
Smoky Quartz (cairngorm). Also much sought after, the colour of this variety ranges from a smoky yellow to brown or almost black. The colour is believed to be the result of partial decomposition of the quartz by exposure to radiation
from radioactive minerals. The presence of aluminium substituting for silicon atoms in the crystal lattice seems also to be essential. Smoky quartz can sometimes be decolorised by heat, the effect becoming noticeable above 225o and rapid above 450o. Some of the colour can be retained in a deeply coloured specimen by stopping the process before it is complete.
Citrine is the yellow to orange variety of quartz. Its colour appears to be due to the presence of small amounts of colloidal hydrated iron (111) oxide. Good specimens are not easy to find at Kingsgate, but some types of smoky quartz, evidently containing the necessary impurity, will turn into citrine when heated.
Amethyst, the much admired violet variety of quartz, is even scarcer at Kingsgate than citrine, which it much resembles chemically. The colour is due to the presence of iron (111) possibly substituting for silicon in the lattice. Strong heat will convert amethyst into an orange citrine.
Quartz with Inclusions. The following have been reported from Kingsgate: rutilated quartz (grass stone) contains fine needles of rutile (TiO2) penetrating the quartz. It has occasionally been found at Kingsgate. Arsenopyrite, bismuth, bismuthinite and molybdenite are fairly frequently found.
Calcite (CaCO3) occurs in white cleavable masses in some pipes.
Muscovite mica, as the variety sericite, is plentiful in the pipes, where it has been produced by the alteration of the original felspar. It can be recognised by its silky lustre, softness and lack of visible crystals.
Topaz and garnet (variety unspecified) have been reported from the dumps. Finding these would have to be regarded as a bonus.


Tuesday, 5 March 2024

THE KINGSGATE MINES 1988 PART 1  

HISTORY OF THE KINGSGATE MINES

Sachs'Mine. Specimens Torn From One Mass of Molybdenite.

When I moved to Glen Innes in January 1988, I began work on the attached report on the Kingsgate mines. This was the place where mining had revealed a great variety of minerals, and it was the sight of these in the Mining Museum and the Australian Museum in Sydney which stimulated me to study Geology and Mineralogy in particular.

In those days there was free access to the mines area, about 30 km east of Glen Innes which made it easy to collect specimens, unlike today. I hope this little volume will both inform and encourage you.

John Paix Glen Innes 1988 ©

Illustrations and many quotations are from Reports, Bulletins etc of the Geological Survey of NSW.

THE KINGSGATE MINES Part 1

 HISTORY OF THE KINGSGATE MINES            

Following the first exploration of the Glen Innes area in 1835 by Duval and Chandler (the "Beardies"), squatters soon moved in and took possession of the more fertile and accessible parts. Kingsgate lies on the eastern side of this more favourable country and was settled by 1848. In those early years, little attention was given to the possibility of valuable minerals being found in the district. Things were soon to change.

The gold rushes which began in 1851 brought enormous numbers of immigrants into the country and inevitably prospectors were drawn to the streams and gullies of New England. Gold was discovered at Nundle in 1852 and east of Tenterfield in 1859. Along with the gold, the miners sometimes found dense black sand, more of a nuisance than anything else. First recognised as the valuable mineral cassiterite (tin oxide) at Dundee in 1853, it was not until 1872 that its potential was realised. In that year the great rushes to Tingha, Elsmore and Emmaville began.

In less than a year, prospectors were scouring New England from Armidale to the Queensland border and beyond, seeking this new "black gold". They found it in a host of places - Tingha, Newstead, Elsmore, Vegetable Creek, Torrington, Bald Nob, Wilson's Downfall, Stanthorpe and many more. As with gold, the rock outcrops from which the alluvial mineral was derived were eagerly sought too, for these offered the possibility of more permanent mines and greater wealth.

So it was that in 1872 prospectors acting on behalf of an Adelaide company came to Kingsgate, where 80 acres of land were secured for the purpose of mining tin. Small quantities of cassiterite were indeed found in the quartz outcrops, but, like the gold miners before them, the tin miners failed to notice or appreciate the other valuable minerals found there. The site was soon abandoned.

In 1877, a stockman on Yarrow Creek Station named J. Feeney picked up a large piece of a metallic mineral in the vicinity of the old tin workings. It was sent to Sydney for identification where it was shown to be native bismuth. About the same time, Hughie Quinn, a prospector, noticed a yellow encrustation on a quartz outcrop on Leatherjacket Hill. (The site later became known as the No. 5 pipe, the famous "One and Nine".) Believing it to be sulfur, he showed it to Mr. W.H. Yates who was at that time mining tin on the Severn River near Bald Nob. Yates determined the mineral to be bismuth ochre (bismite or bismuth oxide, Bi2O3). The specimen was then shown to Mr. Ferguson, a Member of Parliament at that time, who recommended that the land on which the outcrops occurred be secured.

In 1879, Quinn and Ferguson leased 60 acres of the original tin leases for the purpose of mining bismuth. This prompted Feeney to secure a block lower down the gully, in company with John Rush and Mr. Say. Acting on advice from Quinn, Yates visited the area in 1880 and washed rich native bismuth from the rubble of a quartz pipe at a locality near the Yarrow River known locally as the Cattle Camp which he proceeded to lease for mining also. (This was evidently the No. 24 pipe, known as "the Forty" mine.) Meanwhile, Feeney sold his lease to Mr. Lewis, a storekeeper in Glen Innes, who, observing the isolated nature of the leases, suggested that all should be amalgamated. The Kingsgate Bismuth Company was thus formed and the holders then proceeded to obtain leases on the land between their blocks and on adjoining land where quartz outcrops were to be found.

Active prospecting for further quartz outcrops was also carried out by another local group, calling themselves the "Glen Innes Company". They located outcrops overlooked by the Kingsgate Bismuth Company and secured a lease of 25 acres. It was on this land that the famous "Old 45" pipe was later discovered.

The Kingsgate Company worked its mines until 1883, when they sold out to Messrs D. Marks and E. Vickery. Mr. Yates continued on as manager until 1889 when mining ceased, mainly due to the primitive recovery methods in use then. At this time, only bismuth minerals were recovered, the associated molybdenite being discarded. It was during this period that access roads and a water race from the Yarrow River were constructed. The Glen Innes Company followed a similar pattern, closing down operations in 1890 due to poor returns. Over the next few years, Yates continued to mine some bismuth and a number of other small mineral recoveries were made by prospectors.

In 1901, Mr. Valentine Sachs secured the land formerly leased by the Glen Innes Company and mined the main pipe on his block (No. 45) successfully until 1912. By 1907, molybdenite was beginning to contribute significantly to the profitability of the mines.

Marks and Vickery's mines continued to produce ore intermittently until 1905 when the property was sold to Yates. He progressively improved the milling and concentration of the ore. In 1912 Yates erected the Number 40 mill and the Upper mill to process the ore. At this stage 35 men were employed. In 1918 the mines were sold to Kingsgate Molybdenite NL which planned a great expansion of production. It was intended to install a tramway haulage system and to centralise the air compressing plant to supply the various mines with the compressed air necessary to operate mining equipment.

Mr. Sachs sold his lease to the Glen Innes Molybdenite and Bismuth Company in 1912, which had little success in continuing operations. Sachs, meanwhile, took up further mining leases between those of the two companies under the name of the "Sachs of Kingsgate Molybdenite and Bismuth Syndicate". Further leases were secured by him to the south of the existing mines but in 1917 Sachs sold his leases to Thomas Lancaster who continued with limited mining and prospecting.

The outbreak of World War 1 greatly increased the demand for molybdenite, as molybdenum had become a vital metal in the manufacture of hardened steel for guns, tanks etc. Agreements with the British government to purchase molybdenite ran out in 1920 and the price of the mineral dropped so dramatically that there was virtually no market at all for several years. Only ore rich in bismuth had any value and little of this remained in the pipes being mined.

By the commencement of World War 11 the demand for molybdenite was being adequately met by the great mines at Climax, Colorado. The Kingsgate mines met a new need, however, as they became a source of flawless quartz crystals for use in radio equipment. Messrs M Priest, AA Goodwin and H Goodwin were involved in mining at this time but eventually the workings were taken over by AWA and Radio Corporation.

Mr H Quodling managed the quartz mining for AWA and around 10 men were employed extracting crystals from the old dumps with some coming from new work in the old shafts. The market for quartz declined rapidly from 1945 and activity ceased once more.

In 1948, Mr. E. Moskovits, acting for Kingsgate Mining Industries Pty Ltd, began producing molybdenite and wolfram concentrates, mostly by retreating old dump material. This period of production closed in 1952.

In 1966 and again in 1969 the field was investigated for its potential for the development of a low grade open cut mine. After extensive field work and testing by drilling, which brought discouraging results, the area was left to the fossickers once more.

Wednesday, 21 February 2024

Minerama Book 1. MOLYBDENITE 1992

 I've just been through all my numerous blogs, making corrections and improving the overall appearance. I've found lots of links that no longer work and in particular links to downloading the old Minerama books. 

These are important reading for people interested in visiting Glen Innes and so I have decided to put up copies on this blog.They are as issued - no changes have been made. 

I have found it very difficult to copy this document. It looks untidy but at least all the information is there,

Here is number 1 - Molybdenite





Friday, 19 July 2013

KINGSGATE QUARTZ

KINGSGATE QUARTZ

The Kingsgate mines (near Glen Innes, NSW) have been a major source of bismuth and molybdenum since the 1870’s and recent exploration has revealed that economic amounts of these resources still exist.


Much facettable quartz has been found in the dumps right up to the present and would be still if access were permitted
Because of mining exploration in recent years, the public has been refused access to the area except under strict supervision on a few rare occasions such as during Minerama, the annual Glen Innes gem and mineral show.

As a result of Kingsgate's long mining history, there are numerous reports available about the area, all of which make reference to the presence of quartz crystals. Several of my reports are found in this Blog (2024)

Here is a list of easily accessible downloadable references:

Previous references in my Blog:
June 4 2013 DOWNLOADING PDF DOCUMENTS FROM "DIGS",
June 7 2013 The Molybdenum Industry in NSW (Mineral Resources 24, 1916, by EC Andrews) and Molybdenum in NSW (Mineral Resources 43, 1978, by CR Weber, IBL Paterson and DJ Townsend).
July 4 2013 MINERAMA BOOK DOWNLOADS FROM ALF Molybdenite
July 5 2013 MORE USEFUL BOOK DOWNLOADS FROM ALF Kingsgate Mines.

Other references downloadable from DIGS:

Crystal Report 14 (1944) (GS1943/013)

Notes on the Occurrence of Piezoelectric Quartz in Australia with Special Reference to the Kingsgate Field (1944) (GS2009/0915)


 Why not check out my You Tube channel here where you can view gem hunting, mining and general geology videos. 


Thursday, 4 July 2013

MINERAMA BOOK DOWNLOADS FROM ALF

MINERAMA BOOK DOWNLOADS FROM ALF

Since 1990 the Minerama Committee has staged an annual gem, mineral and fossicking show in Glen Innes, NSW Australia. It is one of the largest shows of its kind in the country. From 1992 to 2000 a feature of the show was a theme mineral booklet, which was given away free in the early years and later sold at low cost.


Each issue has two essential parts. The general information about the theme mineral and most of the photographs were supplied by the late Heide Klingbeil while the Glen Innes locality information was compiled by John Paix, who was also the overall editor for the series. 

Remainders were sold at subsequent shows and they are now being made available for free download from the Australian Lapidary Forum (ALF) website. (See listings later on in this blog.)

ALF is a valuable resource for anyone interested in lapidary, gems and minerals in Australia and contains a large collection of files and photographs which grows daily. It is hosted as a free service by Aussie Sapphire Lapidary Warehouse, a progressive business based in Glen Innes. Why not check out these websites and take advantage of the great features they have to offer?


Aussie Sapphires Facebook page: https://www.facebook.com/AussieSapphire

Australian Lapidary Forum: http://www.aussiesapphire.com.au/forum

The Minerama books are no longer downloadble from ALF. You will find them in this Blog for February and March 2024.

Happy reading! 

Why not check out my You Tube channel here where you can view gem hunting, mining and geology videos.